|
CHE 230 Spring 2008 An
Outline of Reactions in the Course (examples
only; not complete; some details must be supplied) |
||
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Starting Material |
Reagents |
Products |
|
1 |
HBr |
|
|
2
|
H3O+ |
|
|
3
|
1) BH3.THF 2) H2O2,
HO- |
|
|
4
|
H2,
catalyst |
|
|
5
|
Br2 |
|
|
6
|
Br2 +
ROH (or HOH) |
|
|
7
|
(= RCOOOH or RCO3H) |
|
|
8 |
1) RCO3H 2) H2O (H+
or HO-) |
|
|
9
|
1) OsO4 2) NaHSO3 or KMnO4, H2O,
HO- |
|
|
10
|
|
|
|
11 HCΞC–CH3 |
|
|
|
12 CH3–CΞC–CH2CH3 |
|
|
|
13
|
HBr (one equiv.) |
|
|
14
|
Br2 (one equiv.) |
|
|
15
|
HBr (two equiv.) |
|
|
16
|
Br2 (2 equiv.) |
|
|
17
|
H2O, HgSO4,
H2SO4 |
|
|
18
|
1)
R2BH 2)
H2O2, HO- |
|
|
19
|
H2, metal catalyst |
CH3CH2CH2CH3 |
|
20
|
H2, Lindlar
catalyst |
|
|
21
|
Na, NH3 |
|
|
22
|
Na+ NH2-,
NH3 |
|
|
23
|
CH3CH2CH2CH2Cl |
|
|
24
|
|
|
|
25
|
1) Nuc: 2) ROH or HOH (SN2) |
|
|
26
|
H+, ROH (or H2O),
HX (SN1) |
|
|
27
|
(also E1 under acidic conditions) |
|
|
28 |
CrO3 or Na2Cr2O7,
H2O, H2SO4 |
|
|
29
|
CrO3, pyridine, HCl (PCC) |
|
|
30 |
H2 / Pd, C |
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