CHE 442G
Spring 2007
Course Outline: Section II

Chpt 5	Standard Thermodynamic Functions
	Calculations of DH, DS, and DG values for phase changes and reactions from tabulated data (including calculations based on Hess's law)
	Correction of DH, DS (and thus DG) values calculated at 298 K to other temperatures using Cp data
	Calculation of difference between DU and DH
	Calculations of absolute entropies from Cp data (including use of the aT^3 law at very low T)
	Differences [Hideal(T,P) - Hreal(T,P)] and [Sideal(T,P) - Sreal(T,P)] (formulas would be given)

Chpt 6	Reaction Equilibria in Mixtures of Ideal Gases
	Interconversion of Kp and DG° values
	Correction of Kp,298 to Kp at other temperatures
	Conversion of Kp values to Kc, Kx, and Kn values
	Equilibrium problems (including solution by method of successive approximations and calculation of )

Chpt 7	One-Component Phase Equilibria
	Determination of f, c, and p values (Gibbs phase rule)
	Use of Trouton's rule
	Location of points on one-component phase diagrams (including triple point, melting and boiling points, critical point)
	Change in vapor and sublimation pressures with T
	Change of boiling and sublimation temperatures with P
	Change in melting point (and any solid-solid transition temperatures) with P
	Calculation of DG (= Dm) values from vapor-pressure data

Chpt 8	Real Gases
	Nonideality: origins, extent
	Use of real-gas equations of state