9-BBN

9-borabicyclo[3.3.1]nonane

ac

acetyl

acac

acetylacetone

AIBN

2,2'-Azobisisobutyronitrile

Ala

alanine (A)

anticlinal

gauche dihedral angle of 120 ¡

Ar

aryl

Arg

arginine (R)

Asn

asparagine (N)

Asp

aspartic acid (D)

Asx

Asn and/or Asp

ATP

adenosine triphosphate

BBN

borabicyclo[3.3.1]nonane

BCME

bis(chloromethyl)ether

BHA

butylated hydroxy anisole

BHT

butylated hydroxy toluene

BINAL-H

2,2'-dihydroxy-1,1'-binaphthyllithium aluminum hydride

BINAP

2,2'bis(diphenylphospinio)-1,1'-binaphthyl

BINOL

1,1'-bi-2,2'-naphthol

bipy

2,2''-bipyridyl

BMS

borane dimethyl sulfide

Bn

benzyl

Boc

t-butoxycarbonyl

BOM

benzyloxymethyl

BOMCl

benzyloxymethyl chloride

bp

boiling point

BPPFA

N,N-dimethyl-1-[1',2-bis(diphenylphosphino)-ferrocenyl)ethylamine

BPPM

N-t-butoxycarbonyl-2-(diphenylphosphino)-ethyl-4-diphenylphospinopyridine

bs

brosyl(4-bromobenenesulfonyl)

BSA

N,O-bis(trimethylsily)acetamide

BSA

bovine serum albumin (more common)

BSTFA

O,N-bis(trimethylsilyl)trifluoroacetamide

BTAM

(triton B) benzyltrimethylammonium hydroxide

Bu

n-butyl

Burgess Reagent

CH3O2CN-SO2N+CH2CH3

Bz

benzoyl

CAN

cerium(IV) ammoniumu nitrate

CAS

cerium(IV) ammoniumu sulfate

Cbz

benzyloxycarbonyl

CD

circular dichroism

CDI

N,N'-Carbonyldiimidazole

CHIRAPHOS

2,3-bis(diphenylphospino)butane

chloramine-T

sodium N-chloro-p-toluenesulfonamide

chloranil

tetrachlorobenzoqinone

Chx

cyclooctatetraene

CI

configurational interaction (comp chem), chemical ionization (MS)

cod

cyclooctadiene

Collman's reagent

disodium iron tetracarbonyl

Common

Abbreviations

cot

cyclooctadiene

Cp

cyclopentadienyl

CRA

complex reducing agent

CSA

camphorsulfonic acid

CSI

chlorosulfonyl isocyanate

CTAB

ceyltrimethylammonium bromide (CH3(CH2)15N+(CH3)3

cy

cyclohexyl

Cys

cystine (C)

d

density

DABCO

1,4-diazabicyclo[2.2.2]octane

Danishefsky diene

1-methoxy-3-trimethylsiloxybuta-1,3-diene

DAST

N,N-diethylaminosulfur trifluoride

dba

dibenzylideneacetone (Ph-CH=CH-)2C=O

DBAD

di-t-butyl azodicarboxylate

DBN

1,5-diazabicyclo[3.4.0]non-5-ene

DBU

1,8-diazabicyclo[5.4.0]undec-7-ene

DCC

dicyclohexylcarbodiimide

DDQ

2,3-dichloro-5,6-dicyano-1,4-benzoquinone

DDT

1,1-bis(p-chlorophenyl)-2,2,2,-trichloroethane

de

diastereomeric excess

DEAC

diethyaluminum chloride

DEAD

diethylazodicarboxylate

des

without (eg. des methyl)

DET

diethyltartrate

DHP

dihydropyran

DIAD

diisopropylazodicarboxylate

DIBAL

diisobutylaluminum hydride (also DIBAL-H)

DIEA

diisopropylethylamine (more common)

dien

dithylenetriamine

diglyme

diethylene glycol dimethyl ether

dimsyl

methylsulfinylmethylide, CH3SOCH2(-)

DIOP

2,3-O-isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane

DIPEA

diisopropylethylamine

diphos

dppe

DIPT

diisopropyltartrate

disiamyl

1,2-dimethylprop-1-yl

DMA

dimethylacetamide

DMAD

dimethylacetalenedicarboxylate

DMAP

4-N-N-dimethylpyridine

DMB

2,6-dimethoxybenzyl

DME

1,2-dimethoxyethane (glyme)

DMF

N,N-dimethylformamide

dmg

diemthylglyoximato

DMI

dimethyimidazole

DMPU

N,N'-dimethypropyleneurea

DMS

dimethylsulfide

DMSO

dimethylsulfoxide

DMTSF

dimethyl(methythio)sulfonium tetrafluoroborate

DNMR

dynamic NMR

DNP

2,4-dinitrophenylhydrazine (derivative)

dppb

1,4-bis(diphenylphosphino)butane

dppe

1,2-bis(diphenylphosphino)ethane

dppf

1,1'-(diphenylphosphino)ferocene

dppp

1,3-bis(diphenylphosphino)propane

DTBP

di-t-butyl peroxide

E

G. Entegen opposite

E

in structures carboalkoxy group (ester)

EDA

ethyl diazoacetate

EDC

1-ethyl-3-(3-dimethyaminopropyl)carbodimide

EDCI

EDC

EDT

1,2-ethanedithiol

EDTA

N,N,N',N'-tetramethylethylenediamine

ee

enantiomeric excess

EE

1-ethoxyethyl

ENDOR

electron nuclear doubel resonance

eschenmoser's salt

(CH3)2NCH2+ I-

esr

electron spin resonance

Et

ethylÊ

ETSA

ethyl timethysilylacetate

Eu(fod)3

tris(1,1,1-trifluoro-7,7-dimethyl-4,6-octane-dion)europium(III)

EWG

electron withdrawing group

EXAFS

extended x-ray absorption fine spectrum

FAB

fast atom bombardment

FID

free induction decay

FMN

flavin mononucleotide

Fp-

cyclopentadienyldicarbonylferrate

FT

Fourier transform

FVP

flash vacuum pyrolysis

GLC

VPC, GC gas-liquid chromatography

Gln

glutamine (Q)

Glu

glutamic acid (E)

Glx

Gln and/or Glu

Gly

glycine (G)

Hex

n-hexyl

His

histadine (H)

HLAPH

horse liver alcohol dehydrogenase

HMDS

hexamethyldisilazane

HMPA

hexamethyphosphoric triamide

HOBt

1-hydroxybenzotriazole

homo

same

HOMO

highest occupied molecular orbital

HOS

hydeoxyamine-O-sulfonic Acid, H2NOSO2OH

HOSu

N-hydroxysuccinamide

HPLC

high performance (pressure) liquid chromatography

Hunig's Base

diisopropylethylamine

Ile

isoleucine (I)

im

Imidazol

Ipc

isopinocamphenyl

IR

infra red

KHMDS

potassium hexamethyldisilazide

LAH

Lithium aluminum hydride

LD50

dose that is lethal to 50% of the subjects

LDA

lithium diisopropylamide

Leu

leucine (L)

LHDMS

lithium hexamethyldisilylazide (also LiHDMS)

LICA

ithium diisopropylcyclohexylamide

LTA

lead tetraacetate

LTMP

lithium 2,2,6,6-tetramethylpiperidide (harpoon base) (also LTMP)

LUMO

lowest occupied molecular orbital

lut

lutadine

Lys

lysine (K)

MA

maleic anhydride

MAD

methyaluminum bis(2,6-di-t-butyl-4-methylphenoxide)

magic methyl

CH3SO3F

MAT

methyaluminum bis(2,4,6-tri-t-butylphenoxide)

m-CPBA

m-Chloroperoxybenzoic acid

Me

methyl

meerwein salt

trialkyloxonium tetrafluoroborate

MEK

methyl ethyl ketone

MEM

2-methoxyethoxymethyl

MEMCl

2-methoxyethoxymethyl chloride

Mes

mesityl (2,4,6-trimethylphen-1-yl)

Met

methionine (M)

MIC

methy isocyanate

MMPP

magnesium monoperoxyphthalate

MOM

methoxymethyl

MOMCl

methoxymethyl chloride

MoOPH

oxodiperoxomolybdenum(pyridine)(hexamethylphospohoric triamde)

mp

melting point

MPM

p-methoxyphenylmethyl

MPMCl

p-methoxyphenylmethyl chloride

Ms

mesyl

MS

mass spectrometry

MS

molecular Sieves

Ms2O

mesyl Anhydride

MTBE

methy t-butyl ether

MTM

methylthiomethyl

MVK

methylvinylketone

n

refractive index

NAD+

nicotinamide adenine dinucleotide

NADH

nicotinamide adenine dinucleotide (reduced)

NaHDMS

sodium hexamethydisilazide

Naph

naphthyl

NBA

N-bromoacetamide

nbd

norbornadiene (bicyclo[2.2.1]hepta-2,5-diene)

NBS

N-bromosuccinimide

NCS

N-chlorosuccinimide

NIS

N-iodosuccinimide

NMO

4-methylmorpholine N-oxide

NMP

N-methyl-2-pyrrolidinone

NMR

nuclear magnetic resonance

nOe

nuclear Overhauser effect

nor

indicates removal of a skeletal atom from a well-known structure

NORPHOS

bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene

Np

see Naph

Ns

nitrobenzene sulfonyl

OBO

bridged carboxylic orthoester

ORD

optical rotary dispersion

oxone

potassium hydrogen persulfate 2KHSO4.K2SO4

PAP

4-pyrrolidinopyridine

PBB

polybrominated biphenyls

PCB

polychlorinated biphenyls

PCC

pyridinium chlorochromate

PDC

pyridinium dichromate

PEG

polyethyleneglycol

pent

n-pentyl

PES

photo electron spectroscopy

PG

prostoglandin

ph

phenyl

Phe

phenylalanine (F)

phen

1,10-phenanthroline

Phth

phthaloyl

Piv

pivaloyl

PLE

pig liver esterase

PMB

p-methoxybenzy

PMDTA

N,N,N',N'',N''-pentamethyldiethylenetriamine

PNB

p-nitrobenzoate

PPA

polyphosphoric acid

PPE

polyphosphate ester

PPTC

pyrophosporyltetrachloride

PPTS

pyridinium p-toluenesulfonate

Pr

n-propyl

Pro

proline (P)

PTAB

phenyltrimethlyammonium perbromide, PhNMe3+Br3-

PTC

Phase Transfer Conditions

PTSA

para-toluene sulfonic acid

pyr

pyridine (also py)

QSAR

quantitative structure-activity relationship

RAMP

(R)-1-amino-2-(methoxymethy)pyrrolidine

Red-Al

sodium bis(2-methoxyethoxy)aluminum hydride

rt

room temperature

salen

bis(salicylidene)ethylenediamine

SAMP

(S)-amino-2-(methoxymethy)pyrrolidine

seco

indicates ring-cleavage product of a well-known structure

selectride

tri-sec-butylborohydride, Li or K salt

SEM

2-(trimethylsilyl)ethoxymethyl

SEMCl

2-(trimethylsilyl)ethoxymethyl chloride

Ser

serine (S)

SET

single electron transfer

Sia

siamyl(3-methyl-2-butyl)

SOMO

singly occupied molecular orbital

St

styrene

Sulfan B

sulfur trioxide (stabilized)

Sulfolane

tetrahydrothiophene-S,S-dioxide

super hydride

sodium triethylborohydride Na(C2H5)3BH

synclinal

gauche dihedral angle of 60 ¡

TASF

tris(diethylamino)sulfonium diflurotrimethylsilicate

TBAB

tetrabutylammonium bromide

TBAD

see DBAD

TBADC

bis(tetrabutylammonium)dichromate

TBAF

tetrabutylammonium fluoride

TBAI

tetrabutylammonium iodide

TBAPI

tetra-n-butylammonium periodate

TBDMS

t-Butyldimethylsilyl

TBDPS

t-Butyldiphenylsilyl

TBDPSCl

t-Butyldiphenylsilyl chloride

TBHP

t-Butylhydroperoxide

TBHP

t-butyl hydroperoxide

TBS

t-Butyldimethylsilyl

TBSCl

t-Butyldimethylsilyl chloride

TBSOTf

t-Butyldimethylsilyl triflate

TCNE

tetracyanoethylene

TCE

2,2,2-trichloroethanol

TFE

2,2,2-trifluroroethanol

TCNQ

7,7,8,8-tetracyanoquinodimethane

TEA

triethylamine

TEBA

triethylbenzylammonium chloride (also TEBAC)

TEMPO

2,2,6,6-tetramethypiperidinoxyl

TES

triethylsilyl

TESCl

triethylsilyl chloride

Tf

triflate (trifluoromethanesulfonyl)

TFA

trifluoroacetic acid

TFAA

trifluoroacetic anhydride

THF

tetrahydrofuran

THP

tetrahydropyran, tetrahydropyranyl

Thr

threonine (T)

Thx

thexy (2,3-dimethy-2-butyl)

TIPS

triisopropylsilyl

TLC

thin Layer Chromatography

TMOF

trimethylorthoformate HC(Ome)3

TMANO

trimethylamine N-oxide

TMM

trimethylene methane

TMEDA

N,N,N',N'-tetramethylethylenediamine

TMG

1,1,3,3-tetramethylguanidine

TMP

2,2,6,6-tetramethypiperidine

TMS

trimethylsilyl

TMSI

trimethylsilyl iodide

TMSCl

trimethylsilyl chloride

Tol

p-tolyl

TPAP

tetrapropylammonium perruthenate

TPP

tetraphenylporphyrin

TPP

triphenylphosphine

Tr

trityl (triphenymethyl)

Trp

tryptophane (W)

triton B

(BTAM) benzyltrimethylammonium hydroxide

troc

2,2,2-trichloroethoxycarbonyl (amine protection labile to reduction)

TRIS

tris(hydroxymethyl)aminomethane

tris

three groups

bis

two groups

TOSMIC

p-toluenesulfonylmethylisocyanide

Ts

tosyl

TsCl

tosyl chloride

TsOH

tosic acid

TTN

thallium(III) nitrate

Tyr

tyrosine (Y)

UHP

ureahydrogen peroxide complex

Val

valine (V)

Z

see Cbz

Z

G. Zusammen (together)