2002 to Present

17.     Tyagi, P.; Li, D.; Holmes, S. M.; Hinds, B. J. “Mechanical Stress Control for the Fabrication of Stable Molecular Electrodes at Patterned Edge of a Metal/Insulator/Metal Junction,” submitted.

16.     Li, D.; Clérac, R.; Roubeau, O.; Harté, E.; Mathonière, C.; Le Bris, R.; Holmes, S. M. "Magnetic and Optical Bistability Driven by Thermally and PhotoInduced Intramolecular Electron Transfer in a Molecular Cobalt-Iron Prussian Blue Analogue,” J. Am. Chem. Soc. 2008, 130, 252-259. pdf

15.     Tyagi, P.; Li, D.; Holmes, S. M.; Hinds, B. J. “Molecular Electrodes at the Exposed Edge of Metal-Insulator-Metal Trilayer Structures," J. Am. Chem. Soc. 2007, 128, 4929-4938. pdf

14.     Li, D.; Parkin, S.; Clérac, R.; Wang, G.; Yee, G. T.; Holmes, S. M. "Structural Distortion and Magnetic Behavior in Cyanide-bridged Fe^III₂Ni^II₂ Complexes," Eur. J. Inorg. Chem. 2007, 1341-1346. pdf

13.     Withers, J. R.; Li, D.; Triplett, J.; Ruschman, C.; Parkin, S.; Wang, G.; Yee, G. T.; Holmes, S. M. “Syntheses, Structures, and Magnetic Characterization of One- and Two-Dimensional Octacyanometalate(V)-Based Networks: {[M^II(DMF)₄]₃[M^V(CN)₈]₂}_n (M^II = Mn, Ni; M^V = Mo, W),” Polyhedron 2007, 26, 2353-2366. pdf

12.     Holmes, S. M., Whelpley, A. S.; Girolami, G. S. “Nanocomposite of a chromium Prussian blue with TiO₂. Redox reactions and the synthesis of Prussian blue molecule-based magnets," Polyhedron 2007, 26, 2291-2298. pdf

11.     Li, D.; Parkin, S.; Wang, G.; Yee, G. T.; Clérac, R.; Wernsdorfer, W.; Holmes, S. M. "An S = 6 Cyano-bridged Octanuclear Fe^III₄Ni^II₄ Complex that Exhibits Slow Relaxation of the Magnetization" J. Am. Chem. Soc. 2006, 128, 4214-4215. pdf (31+ citations)

10.*     Li, D.; Clérac, R.; Parkin, S.; Wang, G.; Yee, G. T.; Holmes, S. M. "An S = 2 Cyano-bridged Trinuclear Fe^III₂Ni^II Single-Molecule Magnet," Inorg. Chem. 2006, 45, 5251-5253. pdf (15+ citations)

9.     Li, D.; Clérac, R.; Parkin, S.; Wang, G.; Yee, G. T.; Holmes, S. M. "Ancillary Ligand Functionalization of Cyanide-bridged S = 6 Fe^III₄Ni^II₄ Complexes for Molecule-Based Electronics Inorg. Chem. 2006, 45, 7569-7571. pdf

8.*     Li, D.; Parkin, S.; Wang, G.; Yee, G. T.; Holmes, S. M. “Synthesis and Spectroscopic and Magnetic Characterization of Tris(3,5-dimethylpyrazol-1-yl)borate Iron Tricyanide Building Blocks, a Cluster, and a One-Dimensional Chain of Squares,” Inorg. Chem. 2006, 45, 1951-1959. pdf (13+ citations)

7.*     Li, D.; Parkin, S.; Wang, G.; Yee, G. T.; Holmes, S. M. “Early Metal Di- and Tricyanometalates: Useful Building Blocks for Constructing Magnetic Clusters, ” Inorg. Chem. 2006, 45, 2773-2775. pdf (12+ citations)

6.     Withers, J. R.; Li, D.; Triplett, J.; Ruschman, C.; Parkin, S.; Wang, G.; Yee, G. T.; Holmes, S. M. “A Two-Dimensional Octacyanomolybdate(V)-Based Ferrimagnet: {[Mn^II(DMF)₄]₃-[Mo^V(CN)₈]₂}_n,” Inorg. Chem. 2006, 45, 4307-4309. pdf (10+ citations)

5.     Li, D.; Ruschman, C.; Parkin, S.; Clérac, R.; Holmes, S. M. "Syntheses, Structures, and Magnetic Characterization of Dicyanometalate(II) Building Blocks: [NEt₄][(Tp*)M^II(CN)₂] [M^II = Cr, Co, Ni; Tp* = hydridotris(3,5-dimethyl-pyrazol-1-yl)borate]", Chem. Commun. 2006, 4036-4038. pdf

4.     Park, K.; Holmes, S. M. “Exchange coupling and contribution of induced orbital angular momentum of low-spin Fe³⁺ ions to magnetic anisotropy in cyanide-bridged Fe₂M₂ molecular magnets: Spin-polarized density-functional calculations," Phys. Rev. B 2006, 74, 224440. pdf

3.     Withers, J. R.; Ruschman, C.; Bojang, P.; Parkin, S.; Holmes, S. M. “Synthesis and Structural Characterization of Bi- and Trimetallic Octacyanometalate(IV) Complexes: [D, L-M^II(en)₃][cis-M^II(en)₂(OH₂)][M^IV(CN)₈]·nH₂O and [cis-M^II(en)₂(OH₂)]₂[(m-NC)₂M^IV(CN)₆]·nH₂O (M^II = Mn, Co, Ni; M^IV = Mo, W),” Inorg. Chem. 2005, 44, 352-358. pdf (10+ citations)

2.*     Li, D.; Parkin, S.; Wang, G.; Yee, G. T.; Prosvirin, A. V.; Holmes, S. M. “Single Molecule Magnets Constructed from Cyanometalates: {[Tp^*Fe^III(CN)₃M^II(DMF)₄]₂[OTf]₂}·2DMF (M^II = Co, Ni),” Inorg. Chem. 2005, 44, 4903-4905. pdf (40+ citations)

1.    Withers, J. R.; Ruschman, C.; Parkin, S.; Holmes, S. M. “One and Three-Dimensional Octacyanometalate(IV) Networks Constructed via a Building Block Approach: {[trans-Ni^II(tn)₂(OH₂)][trans-Ni^II(m-NC)₂(tn)₂]-[(m-NC)₂M^IV(CN)₆]}_∞·3H₂O and Cs₄[Cu^II(OH₂)₄]₂-[Cu^II(NH₃)]₄-[M^IV(CN)₈]₄·2H₂O (M^IV = Mo, W),” Polyhedron 2005, 24, 1845-1854. pdf

Prior to 2002

11.     Holmes, S. M.; McKinley, S. G.; Girolami, G. S.. “Transition Metal p-Toluenesulfonates” Inorg. Synth. 2002, 33, 91-103. pdf

10.     Holmes, S. M.; Schaefer II, D. F.; Lobovsky, E. B.; Wolczanski, P. T. “Synthesis of (^tBu₃SiHN)₂ClW≡WCl(NHSi^tBu₃)₂ and Its Degradation via NH Bond Activation.” J. Am. Chem. Soc. 2001, 123, 10571-10583. pdf

9.       Holmes, S. M.; Girolami, G. S. “Sol-Gel Synthesis of KV^II[Cr^III(CN)₆]·2H₂O: A Crystalline Molecule-Based Magnet with a Magnetic Ordering Temperature above 100 ^oC" J. Am. Chem. Soc. 1999, 121, 5593-5594. pdf (310+ citations)

8.       Awaga, K.; Sekine, T.; Okawa, M.; Fujita, W.; Holmes, S. M.; Girolami, G. S. “High-Pressure Effects on a Manganese Hexacyanomanganate Ferrimagnet with T_N = 29 K” Chem. Phys. Lett. 1998, 293, 352-356. pdf (10+ citations)

7.       Holmes, S. M.; Girolami, G. S. “New Prussian Blue Analogues Constructed from the [Cr(CN)₅NO^3-] and [Cr(CN)₆^4-] Anions.  A Building Block Approach to High T_N Ferrimagnets.” Mol. Cryst. Liq. Cryst. 1997, 305, 279-290. (17+ citations)

6.       Cook, B. R.; Wilkinson, B. B.; Culross, C. C.; Holmes, S. M.; Martinez, L. E.; Garner, C. D. “Hydrogen Transfer Induced Cleavage of Biaryl Bonds” Energy Fuels 1997, 11, 61-75. pdf

5.       Carrano, C. J.; Mohan, M.; Holmes, S. M.; de la Rosa, R.; Butler, A.; Charnock, J. M.; Garner, C. D. “Oxovanadium(V) Alkoxo-Chloro Complexes of the Hydridotripyrazolylborates as Models for the Binding Site in Bromoperoxidase” Inorg. Chem. 1994, 33, 646-655. pdf (70+ citations)

4.       Mayr, A.; Holmes, S. M.; Bastos, C. M. “Preference of Carbonyl Ligands over Isocyanide Ligands in Nucleophile-Induced Coupling with Alkylidyne Ligands” Organometallics 1992, 11, 4358-4362. pdf

3.       Mohan, M.; Holmes, S. M.; Butcher, R. J.; Jasinski, J. P.; Carrano, C. J. “Synthesis, Structure, and Spectroscopic Properties of Vanadium(III) and –(IV) Complexes Containing Hydridotris(pyrazolyl)borate Ligands. 3” Inorg. Chem. 1992, 31, 2029-2034. pdf (63+ citations)

2.       Holmes, S. M.; Carrano, C. J. “Models for the Binding Site in Bromoperoxidase:  Mononuclear Vanadium(V) Phenolate Complexes of the Hydridotris(3,5-dimethyl-pyrazolyl)borate Ligand” Inorg. Chem. 1991, 30, 1231-1235. pdf

1.       Kime-Hunt, E.; Spartalian, K.; Holmes, S.; Mohan, M.; Carrano, C. J. “Vanadium Metabolism in Tunicates:  The Coordination Chemistry of V(III), V(IV), and V(V) with Models for the Tunichromes” J. Inorg. Biochem. 1991, 41, 125-141.